(Triphenylphosphine-κP)[1,1,1-tris(diphenylphosphinomethyl)ethane-κ3P,P′,P′′]copper(I) tetrafluoridoborate
In the title mononuclear CuI complex, [Cu(C18H15P)(C41H39P3)]BF4, the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetrahedral geometry, the distortion arising from the steric hindrance of the phenyl gro...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810007312 |