Channel Confinement of Aromatic Petrochemicals via Aryl–Perfluoroaryl Interactions With a B←N Host

Channel Confinement of Aromatic Petrochemicals via Aryl–Perfluoroaryl Interactions With a B←N Host

We report channel confinement properties of an electron-deficient boron host derived from the orthogonal B←N interaction between a boronic ester and trans-pentafluorostilbazole. The boron host forms one-dimensional channels in the crystalline solid state when crystallized with common electron-rich a...

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Bibliographic Details
Main Authors: Gonzalo Campillo-Alvarado, Megan M. D'mello, Michael A. Sinnwell, Herbert Höpfl, Hugo Morales-Rojas, Leonard R. MacGillivray
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-10-01
Series:Frontiers in Chemistry
Subjects:
boron
boronic acids
boronic esters
self-assembly
host-guest chemistry
crystal engineering
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00695/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2019.00695/full

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