Characteristics and Mechanism of Vinyl Ether Cationic Polymerization in Aqueous Media Initiated by Alcohol/B(C6F5)3/Et2O

Characteristics and Mechanism of Vinyl Ether Cationic Polymerization in Aqueous Media Initiated by Alcohol/B(C6F5)3/Et2O

Aqueous cationic polymerizations of vinyl ethers (isobutyl vinyl ether (IBVE), 2-chloroethyl vinyl ether (CEVE), and n-butyl vinyl ether (n-BVE)) were performed for the first time by a CumOH/B(C6F5)3/Et2O initiating system in an air atmosphere. The polymerization proceeded in a reproducible manner t...

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Bibliographic Details
Main Authors: Jinghan Zhang, Yibo Wu, Kaixuan Chen, Min Zhang, Liangfa Gong, Dan Yang, Shuxin Li, Wenli Guo
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Polymers
Subjects:
aqueous cationic polymerization
suspension polymerization
emulsion polymerization
poly(vinyl ether)
tris(pentafluorophenyl)borane
density functional theory
Online Access:http://www.mdpi.com/2073-4360/11/3/500

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http://www.mdpi.com/2073-4360/11/3/500

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