Synthesis of Isotactic-block-Syndiotactic Poly(methyl Methacrylate) via Stereospecific Living Anionic Polymerizations in Combination with Metal-Halogen Exchange, Halogenation, and Click Reactions

Synthesis of Isotactic-block-Syndiotactic Poly(methyl Methacrylate) via Stereospecific Living Anionic Polymerizations in Combination with Metal-Halogen Exchange, Halogenation, and Click Reactions

Isotactic (it-) and syndiotactic (st-) poly(methyl methacrylate)s (PMMAs) form unique crystalline stereocomplexes, which are attractive from both fundamental and application viewpoints. This study is directed at the efficient synthesis of it- and st-stereoblock (it-b-st-) PMMAs via stereospecific li...

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Bibliographic Details
Main Authors: Naoya Usuki, Kotaro Satoh, Masami Kamigaito
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Polymers
Subjects:
living polymerization
stereospecific polymerization
anionic polymerization
methyl methacrylate
PMMA
stereoblock polymer
stereocomplex
click reaction
isotactic polymer
syndiotactic polymer
Online Access:https://www.mdpi.com/2073-4360/9/12/723

Internet

https://www.mdpi.com/2073-4360/9/12/723

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