Desaturation via Redox-Neutral Hydrogen Transfer Process: Synthesis of 2-Allyl Anilines, Mechanism and Applications

Desaturation via Redox-Neutral Hydrogen Transfer Process: Synthesis of 2-Allyl Anilines, Mechanism and Applications

Summary: An unprecedented desaturation method via redox-neutral hydrogen transfer process has been disclosed under mild conditions for the selective formation of terminal alkene with alkyl diazo compounds and aza-o-QMs. The control experiments and DFT calculations suggest that the visible light was...

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Bibliographic Details
Main Authors: Yang Zheng, Ping Dai, Dafang Gao, Kemiao Hong, Luyao Kou, Shanliang Dong, Jundie Hu, Lihua Qiu, Wenhao Hu, Xiaoguang Bao, Xinfang Xu
Format: Article
Language:English
Published: Elsevier 2020-06-01
Series:iScience
Subjects:
Organic Chemistry
Materials Chemistry
Chemical Synthesis
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004220303539

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http://www.sciencedirect.com/science/article/pii/S2589004220303539

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