Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution feature...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Beilstein-Institut
2008-05-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Online Access: | https://doi.org/10.3762/bjoc.4.18 |