Derivatives of the triaminoguanidinium ion, 3. Multiple N-functionalization of the triaminoguanidinium ion with isocyanates and isothiocyanates

Derivatives of the triaminoguanidinium ion, 3. Multiple N-functionalization of the triaminoguanidinium ion with isocyanates and isothiocyanates

1,2,3-Triaminoguanidinium chloride was combined with benzaldehyde and hydratropic aldehyde to furnish the corresponding tris(imines), which were converted into 1,2,3-tris(benzylamino)guanidinium salts by catalytic hydrogenation in the former, and by borane reduction in the latter case. The resulting...

Full description

Bibliographic Details
Main Authors: Jan Szabo, Kerstin Karger, Nicolas Bucher, Gerhard Maas
Format: Article
Language:English
Published: Beilstein-Institut 2014-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aryl isocyanate
aryl isothiocyanate
carbamoylation
sulfonyl isocyanate
triaminoguanidinium salt
1H-1,2,4-triazole-5(4H)-thione
Online Access:https://doi.org/10.3762/bjoc.10.234

Internet

https://doi.org/10.3762/bjoc.10.234

Similar Items