An approach to the construction of the carbon skeleton of marine nor-sesquiterpenes. Total synthesis of (±)-dehalo-napalilactone

We disclose herein a synthetic approach for the preparation of an unusual carbon skeleton, which was found in nor-sesquiterpenes isolated from marine corals. The main structural feature of this skeleton is the presence of two contiguous quaternary centers, one of them bears a spiro gamma-butyrolacto...

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Bibliographic Details
Main Authors: Diaz Gaspar, Coelho Fernando
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2001-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000300007