Bis(μ4-adamantane-1,3-dicarboxylato-1κO1:2κO1′:3κO3:4κO3′)octacarbonyl-1κ2C,2κ2C,3κ2C,4κ2C-tetrakis[tris(4-methylphenyl)phosphane]-1κP,2κP,3κP,4κP-tetraosmium(I)(2 Os–Os)

Bis(μ4-adamantane-1,3-dicarboxylato-1κO1:2κO1′:3κO3:4κO3′)octacarbonyl-1κ2C,2κ2C,3κ2C,4κ2C-tetrakis[tris(4-methylphenyl)phosphane]-1κP,2κP,3κP,4κP-tetraosmium(I)(2 Os–Os)

The title complex, [{Os2(CO)4(C21H21P)2}2(C12H14O4)2], is a centrosymmetric molecular loop consisting of two Os—Os sawhorse units linked by two adamantane dicarboxylato bridges. It was synthesized by the microwave-mediated reaction between Os3(CO)12 and adamantane-1,3-dicarboxylic acid. In contrast...

Full description

Bibliographic Details
Main Authors: Diego F. Zometa Paniagua, Gregory L. Powell, Cynthia B. Powell, Eric W. Reinheimer
Format: Article
Language:English
Published: International Union of Crystallography 2020-09-01
Series:IUCrData
Subjects:
diosmium carbonyl
sawhorse complex
supramolecular loop
adamantane dicarboxylate ligand
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314620012043

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314620012043

Similar Items