The influence of composition of binary solvent CH<sub>3</sub>CN-H<sub>2</sub>O on the kinetics of oxidation of cyclohexene by p-BENZOQUINONES in solutions of cationic palladium(II) complexes

The influence of composition of binary solvent CH<sub>3</sub>CN-H<sub>2</sub>O on the kinetics of oxidation of cyclohexene by p-BENZOQUINONES in solutions of cationic palladium(II) complexes

During the study of cyclohexene oxidation by p-benzoquinones into cyclohexanone in water-organic solutions of cationic complexes of palladium(II) it was demonstrated that the initial reaction rate R0 depends complicatedly on water molar fraction for three studied solvents: acetonitrile (AN), dimethy...

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Bibliographic Details
Main Authors: D. S. Zakharova, A. N. Semenyako, O. A. Chertkova, A. V. Frolkova, E. A. Katsman, L. G. Bruk, O. N. Temkin
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2015-06-01
Series:Тонкие химические технологии
Subjects:
cyclohexene oxidation, cyclohexanone, palladium complexes, acetonitrile, phase equilibrium.
Online Access:https://www.finechem-mirea.ru/jour/article/view/240

Internet

https://www.finechem-mirea.ru/jour/article/view/240

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