Different route of hydroxide incorporation and thermal stability of new type of water clathrate: X-ray single crystal and Raman investigation

Abstract Chlormayenite Ca12Al14O32[♦4Cl2] (♦-vacancy) is partially hydrated micro porouss mineral with hydroxide groups situated at various crystallographic sites. There are few mechanisms describing its hydration. The first one assumes Cl− substitution by OH− at the center of the structural cages (...

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Bibliographic Details
Main Authors: Mateusz Dulski, Katarzyna M. Marzec, Joachim Kusz, Irina Galuskina, Katarzyna Majzner, Evgeny Galuskin
Format: Article
Language:English
Published: Nature Publishing Group 2017-08-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-017-08152-1