Synthesis and Reactivity of New Aminophenolate Complexes of Nickel

Synthesis and Reactivity of New Aminophenolate Complexes of Nickel

New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new co...

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Bibliographic Details
Main Authors: Siqi Yu, Huan Wang, Jill E. Sledziewski, Venkata N. Madhira, Cyrus G. Takahashi, Michelle K. Leon, Yulia B. Dudkina, Yulia H. Budnikova, David A. Vicic
Format: Article
Language:English
Published: MDPI AG 2014-09-01
Series:Molecules
Subjects:
nickel
cross-coupling
coordination chemistry
paramagnetic complexes
Online Access:http://www.mdpi.com/1420-3049/19/9/13603

Internet

http://www.mdpi.com/1420-3049/19/9/13603

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