Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds

Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds

N-Alkyl-N-chlorosulfonamides add to alkenes under copper(I) catalysis. In reactions of styrene derivatives with terminal double bonds the addition products were obtained in excellent yield and high regioselectivity. Lower yields are obtained in addition reactions to non-aromatic alkenes. The reactio...

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Bibliographic Details
Main Authors: Gerold Heuger, Richard Göttlich
Format: Article
Language:English
Published: Beilstein-Institut 2015-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
addition reactions
catalysis
N-chlorosulfonamides
haloamination
radical reaction
Online Access:https://doi.org/10.3762/bjoc.11.136

Internet

https://doi.org/10.3762/bjoc.11.136

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