New Rigid Polycyclic Bis(phosphane) for Asymmetric Catalysis

New Rigid Polycyclic Bis(phosphane) for Asymmetric Catalysis

A simple, highly efficient synthesis of a series of novel chiral non-racemic rigid tetracyclic phosphorus ligands, applicable in important chemical asymmetric transformations, was performed. In a tandem cross-coupling/C-H bond activation reaction, a well-recognised and readily available ligand <i...

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Bibliographic Details
Main Authors: K. Michał Pietrusiewicz, Katarzyna Szwaczko, Barbara Mirosław, Izabela Dybała, Radomir Jasiński, Oleg M. Demchuk
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Molecules
Subjects:
bis(phosphane) palladium complex
metallacycle
NORPHOS
allylic alkylation
asymmetric catalysis
chiral phosphines
C-H bond activation
polycyclic compounds
stereoselective synthesis
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/24/3/571

Internet

https://www.mdpi.com/1420-3049/24/3/571

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