P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

Chiral phosphorus ligands have been widely used in transition metal-catalyzed asymmetric reactions. Herein, we report a new synthesis approach of chiral biaryls containing a phosphorus moiety using P(O)R2-directed Pd-catalyzed C–H activation; the functionalized products are produced with good enanti...

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Bibliographic Details
Main Authors: Rong-Bin Hu, Hong-Li Wang, Hong-Yu Zhang, Heng Zhang, Yan-Na Ma, Shang-dong Yang
Format: Article
Language:English
Published: Beilstein-Institut 2014-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
chiral synthesis
Pd-catalysis
organophosphorus
phosphorus ligands
P(O)R2-directing
Online Access:https://doi.org/10.3762/bjoc.10.215

Internet

https://doi.org/10.3762/bjoc.10.215

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