Mirror-Symmetry-Breaking in Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-biphenyl] (PF8P2) is Susceptible to Terpene Chirality, Achiral Solvents, and Mechanical Stirring

Mirror-Symmetry-Breaking in Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-biphenyl] (PF8P2) is Susceptible to Terpene Chirality, Achiral Solvents, and Mechanical Stirring

Solvent chirality transfer of (S)-/(R)-limonenes allows the instant generation of optically active PF8P2 aggregates with distinct circular dichroism (CD)/circularly polarized luminescence (CPL) amplitudes with a high quantum yield of 16–20%. The present paper also reports subtle mirror-symmetry-brea...

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Bibliographic Details
Main Authors: Ayako Nakao, Yoshifumi Kawagoe, Yoko Nakano, Michiya Fujiki
Format: Article
Language:English
Published: MDPI AG 2013-06-01
Series:Molecules
Subjects:
limonene
mirror symmetry breaking
polymer
chirality
optically active
circular dichroism
circularly polarized luminescence
vortex
parity violation
homochirality
Online Access:http://www.mdpi.com/1420-3049/18/6/7035

Internet

http://www.mdpi.com/1420-3049/18/6/7035

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