Isolation and evolution of labile sulfur allotropes via kinetic encapsulation in interactive porous networks

Isolation and evolution of labile sulfur allotropes via kinetic encapsulation in interactive porous networks

The isolation and characterization of small sulfur allotropes have long remained unachievable because of their extreme lability. This study reports the first direct observation of disulfur (S2) with X-ray crystallography. Sulfur gas was kinetically trapped and frozen into the pores of two Cu-based p...

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Bibliographic Details
Main Authors: Hakuba Kitagawa, Hiroyoshi Ohtsu, Aurora J. Cruz-Cabeza, Masaki Kawano
Format: Article
Language:English
Published: International Union of Crystallography 2016-07-01
Series:IUCrJ
Subjects:
sulfur
kinetic trapping
porous coordination networks
X-ray diffraction
allotropes
metal–organic frameworks
MOFs
coordination polymers
transient chemical species
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2052252516008423

Internet

http://scripts.iucr.org/cgi-bin/paper?S2052252516008423

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