Mechanochemical Preparation of Cobalt Nanoparticles through a Novel Intramolecular Reaction in Cobalt(II) Complexes

A novel solid state reaction involving a series of cobalt(II) hydrazine-azides has been used to prepare metallic cobalt nanoparticles. The reactions of [Co(N2H4)(N3)2], [Co(N2H4)2(N3)2], and [Co(N2H4)(N3)Cl]·H2O via NaOH, KOH as reactants were carried out in the solid state. These complexes undergo...

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Bibliographic Details
Main Authors: Seyed Abolghasem Kahani, Massumeh Khedmati
Format: Article
Language:English
Published: Hindawi Limited 2015-01-01
Series:Journal of Nanomaterials
Online Access:http://dx.doi.org/10.1155/2015/246254