Reactivity of Mononuclear and Dinuclear Gold(I) Amidinate Complexes with CS2 and CsBr3
To probe the reactivity of gold-nitrogen bonds, we have examined the insertion chemistry with carbon disulfide (CS2) as well as oxidation with cesium tribromide (CsBr3) with Au(I) amidinate complexes. The reaction of Ph3PAuCl with Na[(2,6-Me2C6H3N)2C(H)] yields the mononuclear, two-coordinate gold...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2014-10-01
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| Series: | Inorganics |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2304-6740/2/4/540 |