Crystal structure of 2-(2,6-diisopropylphenyl)-N,N-diethyl-3,3-dimethyl-2-azaspiro[4.5]decan-1-amine: a diethylamine adduct of a cyclic(alkyl)(amino)carbene (CAAC)

Crystal structure of 2-(2,6-diisopropylphenyl)-N,N-diethyl-3,3-dimethyl-2-azaspiro[4.5]decan-1-amine: a diethylamine adduct of a cyclic(alkyl)(amino)carbene (CAAC)

The structure of the title compound, C27H46N2, at 93 K has monoclinic (P21/n) symmetry. The title compound was prepared by treatment of 2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]dec-1-en-2-ium hydrogen dichloride with two equivalents of lithium diethylamide. Characterization of the title...

Full description

Bibliographic Details
Main Authors: Roxanne A. Naumann, Joseph W. Ziller, Allegra L. Liberman-Martin
Format: Article
Language:English
Published: International Union of Crystallography 2021-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclic(alkyl)(amino)carbene
carbene reactivity
n—h bond activation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021007854

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989021007854

Similar Items