The Natural Product Lepidiline A as an <i>N</i>-Heterocyclic Carbene Ligand Precursor in Complexes of the Type [Ir(cod)(NHC)PPh<sub>3</sub>)]X: Synthesis, Characterisation, and Application in Hydrogen Isotope Exchange Catalysis

The Natural Product Lepidiline A as an <i>N</i>-Heterocyclic Carbene Ligand Precursor in Complexes of the Type [Ir(cod)(NHC)PPh<sub>3</sub>)]X: Synthesis, Characterisation, and Application in Hydrogen Isotope Exchange Catalysis

A range of iridium(I) complexes of the type [Ir(cod)(NHC)PPh<sub>3</sub>)]X are reported, where the <i>N</i>-heterocyclic carbene (NHC) is derived from the naturally-occurring imidaozlium salt, Lepidiline A (1,3-dibenzyl-4,5-dimethylimidazolium chloride). A range of complexes...

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Bibliographic Details
Main Authors: Alison R. Cochrane, Alan R. Kennedy, William J. Kerr, David M. Lindsay, Marc Reid, Tell Tuttle
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Catalysts
Subjects:
iridium
<i>n</i>-heterocyclic carbene
hydrogen isotope exchange
deuterium
Online Access:https://www.mdpi.com/2073-4344/10/2/161

Internet

https://www.mdpi.com/2073-4344/10/2/161

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