Conduction and Electrostriction of Polymers Induced by High Electric Fields

After reviewing the new physics and chemistry in high electrostatic fields we use density functional theory to show that in fields around 1.5 V/Å the bandgap of polythiophene reduces to zero leading to field-induced metallization. In poly(ethylene glycol), on the other hand, such fields lead to gian...

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Bibliographic Details
Main Authors: Hans Jürgen Kreuzer, Markus Karahka
Format: Article
Language:English
Published: MDPI AG 2010-12-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/3/1/51/