Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study

In recent years, cyclic silicon-stereogenic silanes were successfully employed as stereoinducers in transition metal-catalyzed asymmetric transformations as exemplified by (1) the hydrosilylation of alkenes constituting a chirality transfer from silicon to carbon and (2) the kinetic resolution of ra...

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Bibliographic Details
Main Authors: Sebastian Rendler, Martin Oestreich
Format: Article
Language:English
Published: Beilstein-Institut 2007-02-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-3-9