Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
In recent years, cyclic silicon-stereogenic silanes were successfully employed as stereoinducers in transition metal-catalyzed asymmetric transformations as exemplified by (1) the hydrosilylation of alkenes constituting a chirality transfer from silicon to carbon and (2) the kinetic resolution of ra...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2007-02-01
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Series: | Beilstein Journal of Organic Chemistry |
Online Access: | https://doi.org/10.1186/1860-5397-3-9 |