Synthesis of Novel Sterically Demanding Carbo- and Heterocyclic β-Ketoesters

Synthesis of Novel Sterically Demanding Carbo- and Heterocyclic β-Ketoesters

We present an easy method for the synthesis of β-ketoesters starting from variouscarbocyclic and heterocyclic carboxylic acids and esters. The β-ketoester side-chain wasintroduced by a sequence involving α-deprotonation and quenching with CO2, conversion tothe corresponding acid chloride an...

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Bibliographic Details
Main Authors: Peter Stanetty, Thomas C. M. Fischer, Marko D. Mihovilovic
Format: Article
Language:English
Published: MDPI AG 2006-05-01
Series:Molecules
Subjects:
Chain elongation
β-ketoesters
ethyl acetate
heterocyclic esters
Online Access:http://www.mdpi.com/1420-3049/11/5/357/

Internet

http://www.mdpi.com/1420-3049/11/5/357/

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