Synthesis, Structures and Properties of Molecular Conductors Based on Bis-Fused Donors Composed of (Thio)Pyran-4-ylidene-1,3-dithiole and Tetraselenafulvalene

Synthesis, Structures and Properties of Molecular Conductors Based on Bis-Fused Donors Composed of (Thio)Pyran-4-ylidene-1,3-dithiole and Tetraselenafulvalene

Bis-fused donors composed of (thio)pyran-4-ylidene-1,3-dithiole and tetraselenafulvalene (1a, 2a) and their bis(methylthio) derivatives (1b, 2b) were synthesized. Cyclic voltamograms of all the donors consisted of four pairs of one-electron redox waves, and it was suggested that a positive charge of...

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Bibliographic Details
Main Authors: Yohji Misaki, Takashi Shirahata, Masaki Watanabe, Minoru Ashizawa, Ken-ichi Ishidzu
Format: Article
Language:English
Published: MDPI AG 2012-08-01
Series:Crystals
Subjects:
molecular conductor
tetrathiapentalene
pyran
thiopyran
tetraselenafulvalene
cyclic voltammetry
X-ray structure analysis
band calculation
electrical conductivity
intramolecular charge disproportionation
Online Access:http://www.mdpi.com/2073-4352/2/3/1092

Internet

http://www.mdpi.com/2073-4352/2/3/1092

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