Integrated Cobaloxime and Mesoporous Silica-Supported Ruthenium/Diamine Co-Catalysis for One-Pot Hydration/Reduction Enantioselective Sequential Reaction of Alkynes

Integrated Cobaloxime and Mesoporous Silica-Supported Ruthenium/Diamine Co-Catalysis for One-Pot Hydration/Reduction Enantioselective Sequential Reaction of Alkynes

This study developed a cost-efficient hydration/asymmetric transfer hydrogenation (ATH) process for the one-pot synthesis of valuable chiral alcohols from alkynes. During this process, the initial homogeneous cobaloxime-catalyzed hydration of alkynes was followed by heterogeneous Ru/diamine-catalyze...

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Bibliographic Details
Main Authors: Zeyang Liu, Yongjie Wang, Kaihong Liu, Shanshan Wang, Haocheng Liao, Yuanli Zhu, Baoming Hou, Chunxia Tan, Guohua Liu
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-09-01
Series:Frontiers in Chemistry
Subjects:
asymmetric catalysis
heterogeneous catalysts
hydration
transfer hydrogenation
silica
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.732542/full

Internet

https://www.frontiersin.org/articles/10.3389/fchem.2021.732542/full

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