Crystal structure of tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-bis[(2-methylbenzonitrile-κN)rhodium(II)](Rh—Rh)

Crystal structure of tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-bis[(2-methylbenzonitrile-κN)rhodium(II)](Rh—Rh)

The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(C8H7N)2], exhibits inversion symmetry. The four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner with two N atoms and two O atoms coordinating to each RhII atom trans to one another. The Neq—Rh—Rh—Oeq t...

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Bibliographic Details
Main Authors: Cassandra T. Eagle, Nkongho Atem-Tambe, Kenneth K. Kpogo, Jennie Tan, Kevin M. Cook
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
RhII complex
dirhodium core
acetamidate ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814017930

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http://scripts.iucr.org/cgi-bin/paper?S1600536814017930

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