Dual Geometry Schemes in Tetrel Bonds: Complexes between TF<sub>4</sub> (T = Si, Ge, Sn) and Pyridine Derivatives
When an N-base approaches the tetrel atom of TF<sub>4</sub> (T = Si, Ge, Sn) the latter molecule deforms from a tetrahedral structure in the monomer to a trigonal bipyramid. The base can situate itself at either an axial or equatorial position, leading to two different equilibrium geomet...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-01-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/24/2/376 |