Highly Active and Selective Supported Rhenium Catalysts for Aerobic Oxidation of n-Hexane and n-Heptane

Highly Active and Selective Supported Rhenium Catalysts for Aerobic Oxidation of n-Hexane and n-Heptane

A series of derivative C-scorpionate rhenium complexes, i.e., [ReCl2{NNC(O)C6H5}(Hpz)(PPh3)2] (A) (where Hpz is pyrazole), [ReCl2{NNC(O)C6H5}(Hpz)2(PPh3)] (B), [ReClF{NNC(O)C6H5}(Hpz)2(PPh3)] (C), and their precursor [ReOCl3(PPh3)2] (D), immobilized on 3-aminopropyl-functionalized silica have been p...

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Bibliographic Details
Main Authors: Gopal S. Mishra, Elisabete C. B. A. Alegria, Armando J. L. Pombeiro, Luísa M. D. R. S. Martins
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Catalysts
Subjects:
rhenium
scorpionate derivative
immobilization
supported catalysis
n-alkane
oxidation
molecular oxygen
product selectivity
radical mechanism
Online Access:http://www.mdpi.com/2073-4344/8/3/114

Internet

http://www.mdpi.com/2073-4344/8/3/114

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