Indium-Catalyzed Cycloisomerization of 1,6-Cyclohexenylalkynes

Indium-Catalyzed Cycloisomerization of 1,6-Cyclohexenylalkynes

Efficient four- and five-step routes to access functionalized bicyclo[3.2.1]oct-2-ene and bicyclo[3.3.1]nonadiene via indium-mediated cycloisomerization of 1,6-enynes has been developed. This atom-economical catalytic process was optimized and relied on the efficiency of InCl<sub>3</sub>...

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Bibliographic Details
Main Authors: Vincent Davenel, Chloé Puteaux, Christian Nisole, Fabien Fontaine-Vive, Jean-Marie Fourquez, Véronique Michelet
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Catalysts
Subjects:
indium
cycloisomerization reaction
1,6-enyne
catalysis
atom economy
Online Access:https://www.mdpi.com/2073-4344/11/5/546

Internet

https://www.mdpi.com/2073-4344/11/5/546

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