LiGe(SiMe3)3: A New Substituent for the Synthesis of Metalloid Tin Clusters from Metastable Sn(I) Halide Solutions

LiGe(SiMe3)3: A New Substituent for the Synthesis of Metalloid Tin Clusters from Metastable Sn(I) Halide Solutions

The most fruitful synthetic route to metalloid tin clusters applies the disproportionation reaction of metastable Sn(I) halide solutions, whereby Si(SiMe3)3 is mostly used as the stabilizing substituent. Here, we describe the synthesis and application of the slightly modified substituent Ge(SiMe3)3,...

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Bibliographic Details
Main Authors: Mareike Binder, Claudio Schrenk, Theresa Block, Rainer Pöttgen, Andreas Schnepf
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Molecules
Subjects:
co-condensation
disproportionation
germanium
tin
Mössbauer spectroscopy
bulky substituents
metalloid clusters
nanoscaled clusters
Online Access:http://www.mdpi.com/1420-3049/23/5/1022

Internet

http://www.mdpi.com/1420-3049/23/5/1022

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