Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides

Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides

A convenient Rh(III)-catalyzed C-H activation and cascade [4+2] annulation for the synthesis of naphthalenone sulfoxonium ylides has been developed. This method features perfect regioselectivity, mild and redox-neutral reaction conditions, and broad substrate tolerance with good to excellent yields....

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Bibliographic Details
Main Authors: Xiaohan Song, Xu Han, Rui Zhang, Hong Liu, Jiang Wang
Format: Article
Language:English
Published: MDPI AG 2019-05-01
Series:Molecules
Subjects:
rhodium(III)
sulfoxonium ylides
naphthols
Online Access:https://www.mdpi.com/1420-3049/24/10/1884

Internet

https://www.mdpi.com/1420-3049/24/10/1884

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