Role of hydrogen bonding in hysteresis observed in sorption-induced swelling of soft nanoporous polymers

Water uptake of natural polymers is accompanied by swelling and changes in the internal structure of the polymeric system but the exact mechanism of water-uptake and swelling remained unknown. Here the authors use atom-scale simulations to identify a molecular mechanism which is responsible for hyst...

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Bibliographic Details
Main Authors: Mingyang Chen, Benoit Coasne, Robert Guyer, Dominique Derome, Jan Carmeliet
Format: Article
Language:English
Published: Nature Publishing Group 2018-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-05897-9