Enantio- and Periselective Nitroalkene Diels-Alder Reactions Catalyzed by Helical-Chiral Hydrogen Bond Donor Catalysts

Enantio- and Periselective Nitroalkene Diels-Alder Reactions Catalyzed by Helical-Chiral Hydrogen Bond Donor Catalysts

Helical-chiral double hydrogen bond donor catalysts promote the nitroalkene Diels-Alder reaction in an enantio- and periselective manner. This represents the first asymmetric catalytic nitroalkene Diels-Alder reaction via LUMO-lowering catalysis. To gain an insight into this new process, the substra...

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Bibliographic Details
Main Authors: Zhili Peng, Maurice J. Narcis, Norito Takenaka
Format: Article
Language:English
Published: MDPI AG 2013-08-01
Series:Molecules
Subjects:
asymmetric catalysis
nitroalkene
Diels-Alder reaction
helical chirality
Online Access:http://www.mdpi.com/1420-3049/18/8/9982

Internet

http://www.mdpi.com/1420-3049/18/8/9982

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