Synthesis, spectroscopic characterization and thermogravimetric analysis of two series of substituted (metallo)tetraphenylporphyrins

Synthesis, spectroscopic characterization and thermogravimetric analysis of two series of substituted (metallo)tetraphenylporphyrins

Subsequent treatment of H2TPP(CO2H)4 (tetra(p-carboxylic acid phenyl)porphyrin, 1) with an excess of oxalyl chloride and HNR2 afforded H2TPP(C(O)NR2)4 (R = Me, 2; iPr, 3) with yields exceeding 80%. The porphyrins 2 and 3 could be converted to the corresponding metalloporphyrins MTPP(C(O)NR2)4 (R = M...

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Bibliographic Details
Main Authors: Rasha K. Al-Shewiki, Carola Mende, Roy Buschbeck, Pablo F. Siles, Oliver G. Schmidt, Tobias Rüffer, Heinrich Lang
Format: Article
Language:English
Published: Beilstein-Institut 2017-06-01
Series:Beilstein Journal of Nanotechnology
Subjects:
electrospray ionization mass spectrometry
IR spectroscopy
metalloporphyrin
porphyrin
thermogravimetry
UV–vis spectroscopy
Online Access:https://doi.org/10.3762/bjnano.8.121

Internet

https://doi.org/10.3762/bjnano.8.121

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