Copper-Catalyzed Synthesis of Unsymmetrical Diorganyl Chalcogenides (Te/Se/S) from Boronic Acids under Solvent-Free Conditions

Copper-Catalyzed Synthesis of Unsymmetrical Diorganyl Chalcogenides (Te/Se/S) from Boronic Acids under Solvent-Free Conditions

The efficient and mild copper-catalyzed synthesis of unsymmetrical diorganyl chalcogenides under ligand- and solvent-free conditions is described. The cross-coupling reaction was performed using aryl boric acids and 0.5 equiv. of diorganyl dichalcogenides (Te/Se/S) in the presence of 3 mol % of CuI...

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Bibliographic Details
Main Authors: Sumbal Saba, Giancarlo Vaccari Botteselle, Marcelo Godoi, Tiago Elias Allievi Frizon, Fábio Zazyki Galetto, Jamal Rafique, Antonio L. Braga
Format: Article
Language:English
Published: MDPI AG 2017-08-01
Series:Molecules
Subjects:
selenide
telluride
boronic acid
solvent-free
cross-coupling
CuI
selenium
tellurium
Online Access:https://www.mdpi.com/1420-3049/22/8/1367

Internet

https://www.mdpi.com/1420-3049/22/8/1367

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