A new initiating system based on [(SiMes)Ru(PPh3)(Ind)Cl2] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
The homopolymerization and copolymerization of styrene and methyl methacrylate, initiated for the first time by the combination of azo-bis-isobutyronitrile (AIBN) with [(SiMes)Ru(PPh3)(Ind)Cl2] complex. The reactions were successfully carried out, on a large scale, in presence this complex at 80 °C....
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Taylor & Francis Group
2017-01-01
|
Series: | Designed Monomers and Polymers |
Subjects: | |
Online Access: | http://dx.doi.org/10.1080/15685551.2016.1231049 |