Softening the Donor-Set: From [Cu(P^P)(N^N)][PF6] to [Cu(P^P)(N^S)][PF6]

Softening the Donor-Set: From [Cu(P^P)(N^N)][PF6] to [Cu(P^P)(N^S)][PF6]

We report the synthesis and characterization of [Cu(P^P)(N^S)][PF6] complexes with P^P = bis(2-(diphenylphosphino)phenyl) ether (POP) or 4,5-bis(diphenylphosphino)-9,9- dimethylxanthene (xantphos) and N^S = 2-(iso-propylthio)pyridine (iPrSpy) or 2-(tert-butylthio)pyridine (tBuSpy). The single crysta...

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Bibliographic Details
Main Authors: Isaak Nohara, Alessandro Prescimone, Catherine E. Housecroft, Edwin C. Constable
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Inorganics
Subjects:
Copper
coordination complex
2-(alkylthio)pyridine
bis(phosphane)
X-ray structure
dynamic behavior
Online Access:http://www.mdpi.com/2304-6740/7/1/11

Internet

http://www.mdpi.com/2304-6740/7/1/11

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