Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides

Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides

New hexanuclear nickel(II) silsesquioxane [(PhSiO1.5)12(NiO)6(NaCl)] (1) was synthesized as its dioxane-benzonitrile-water complex (PhSiO1,5)12(NiO)6(NaCl)(C4H8O2)13(PhCN)2(H2O)2 and studied by X-ray and topological analysis. The compound exhibits cylinder-like type of molecular architecture and rep...

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Bibliographic Details
Main Authors: Alexey N. Bilyachenko, Alexey I. Yalymov, Lidia S. Shul’pina, Dalmo Mandelli, Alexander A. Korlyukov, Anna V. Vologzhanina, Marina A. Es’kova, Elena S. Shubina, Mikhail M. Levitsky, Georgiy B. Shul’pin
Format: Article
Language:English
Published: MDPI AG 2016-05-01
Series:Molecules
Subjects:
metal silsesquioxane
X-ray analysis
topological analysis
oxidation
alkanes
alcohols
meta-chloroperoxybenzoic acid (MCPBA)
Online Access:http://www.mdpi.com/1420-3049/21/5/665

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http://www.mdpi.com/1420-3049/21/5/665

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