trans-(Pyrimidine-2-thiolato-κ2N,S)[tris(2-aminoethyl)amine-κ4N,N′,N′′,N′′′]cobalt(III) chloride hexafluoridophosphate

In the title compound, [Co(C4H3N2S)(C6H18N4)](Cl)PF6, the CoIII ion is coordinated by a tripod-like tetradentate ligand and a monoanionic N,S-bidentate ligand in an approximately octahedral CoN4OS geometry. The anionic S atom of the pyrimidine-2-thiolate (pymt) ligand is coordinated in the trans pos...

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Bibliographic Details
Main Authors: Keisuke Fujihara, Toshiaki Yonemura
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809032395