Bis(N′-{(E)-[(2E)-1,3-diphenylprop-2-en-1-ylidene]amino}-N-ethylcarbamimidothioato-κ2N′,S)zinc(II): crystal structure and Hirshfeld surface analysis

Bis(N′-{(E)-[(2E)-1,3-diphenylprop-2-en-1-ylidene]amino}-N-ethylcarbamimidothioato-κ2N′,S)zinc(II): crystal structure and Hirshfeld surface analysis

The title ZnII complex, [Zn(C18H18N3S)2], (I), features two independent but chemically equivalent molecules in the asymmetric unit. In each, the thiosemicarbazonate monoanion coordinates the ZnII atom via the thiolate-S and imine-N atoms, with the resulting N2S2 donor set defining a distorted tetrah...

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Bibliographic Details
Main Authors: Ming Yueh Tan, Karen A. Crouse, Thahira B. S. A. Ravoof, Mukesh M. Jotani, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2017-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zinc
hydrogen bonding
thiosemicarbazone
Hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017008064

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989017008064

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