Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties

Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties

Abstract The α‐metallated ylides [Ph3P−C−Z]−M+ (with Z=SO2Tol or CN and M=Na or K) were used as versatile nucleophiles for the facile access to ylide‐substituted compounds. Halogenations, alkylations, carbonylations and functionalization reactions with main group element halides were easily accompli...

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Bibliographic Details
Main Authors: Christopher Schwarz, Dr. Thorsten Scherpf, Ilja Rodstein, Dr. Julia Weismann, Dr. Kai‐Stephan Feichtner, Prof. Dr. Viktoria H. Gessner
Format: Article
Language:English
Published: Wiley-VCH 2019-05-01
Series:ChemistryOpen
Subjects:
ylides
carbanions
alkali metals
structure elucidation
synthesis
Online Access:https://doi.org/10.1002/open.201900094

Internet

https://doi.org/10.1002/open.201900094

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