Fritsch–Buttenberg–Wiechell rearrangement of magnesium alkylidene carbenoids leading to the formation of alkynes

A series of 1-heteroatom-substituted vinyl <i>p</i>-tolyl sulfoxides were prepared and treated with organometallic reagents to evaluate which combination of sulfoxides and organometallic reagents yielded alkynes the most efficiently. The use of 1-chlorovinyl <i>p</i>-tolyl su...

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Bibliographic Details
Main Authors: Tsutomu Kimura, Koto Sekiguchi, Akane Ando, Aki Imafuji
Format: Article
Language:English
Published: Beilstein-Institut 2021-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.17.94