Conversion of Aryl Iodides into Aryliodine(III) Dichlorides by an Oxidative Halogenation Strategy Using 30% Aqueous Hydrogen Peroxide in Fluorinated Alcohol

Conversion of Aryl Iodides into Aryliodine(III) Dichlorides by an Oxidative Halogenation Strategy Using 30% Aqueous Hydrogen Peroxide in Fluorinated Alcohol

Oxidative chlorination with HCl/H2O2 in 1,1,1-trifluoroethanol was used to transform aryl iodides into aryliodine(III) dihalides. In this instance 1,1,1-trifluoroethanol is not only the reaction medium, but is also an activator of hydrogen peroxide for the oxidation of hydrochloric acid to molecular...

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Bibliographic Details
Main Authors: Ajda Podgoršek, Jernej Iskra
Format: Article
Language:English
Published: MDPI AG 2010-04-01
Series:Molecules
Subjects:
oxidative halogenation
hydrogen peroxide
fluorinated alcohol
hypervalent iodine halides
chlorination
Online Access:http://www.mdpi.com/1420-3049/15/4/2857/

Internet

http://www.mdpi.com/1420-3049/15/4/2857/

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