New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2′-Bis(aminomethyl)-1,1′-Binaphthyl

New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2′-Bis(aminomethyl)-1,1′-Binaphthyl

As a candidate for bifunctional asymmetric catalysts containing a half-sandwich C–N chelating Ir(III) framework (azairidacycle), a dinuclear Ir complex with an axially chiral linkage is newly designed. An expedient synthesis of chiral 2,2′-bis(aminomethyl)-1,1′-binaphthyl (<b>1</b>) from...

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Bibliographic Details
Main Authors: Yasuhiro Sato, Yuichi Kawata, Shungo Yasui, Yoshihito Kayaki, Takao Ikariya
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Molecules
Subjects:
bifunctional catalyst
metal-ligand cooperation
dinuclear complex
iridacycle
cyclometalation
asymmetric transfer hydrogenation
Online Access:https://www.mdpi.com/1420-3049/26/4/1165

Internet

https://www.mdpi.com/1420-3049/26/4/1165

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