The quaternary thiophosphate, Cs0.49NbPS6, caesium hexathioniobiophosphate(V), has been synthesized by the reactive halide flux method. The title compound is isotypic with Rb0.46TaPS6 and is made up of a bicapped trigonal–biprismatic [Nb2S12] unit and a tetrahedral [PS4] group. The [Nb...

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Bibliographic Details
Main Authors: Hoseop Yun, Yonghee Lee, Eunsil Lee
Format: Article
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810052724