Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition

Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition

Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La2@Ih-C80. NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The electroni...

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Bibliographic Details
Main Authors: Takeshi Akasaka, Yutaka Maeda, Chika I. Someya, Takahiro Tsuchiya, Tsukasa Nakahodo, Michio Yamada
Format: Article
Language:English
Published: MDPI AG 2011-11-01
Series:Molecules
Subjects:
chemical functionalization
La2@Ih-C80
carbohydrate
diazirine
glycoconjugate
Online Access:http://www.mdpi.com/1420-3049/16/11/9495/

Internet

http://www.mdpi.com/1420-3049/16/11/9495/

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