Isolation of a Nitromethane Anion in the Calix-shaped Inorganic Cage

Isolation of a Nitromethane Anion in the Calix-shaped Inorganic Cage

A calix-shaped polyoxometalate, [V<sub>12</sub>O<sub>32</sub>]<sup>4−</sup> (<b>V12</b>), stabilizes an anion moiety in its central cavity. This molecule-sized container has the potential to control the reactivity of an anion. The highly-reactive cyana...

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Bibliographic Details
Main Authors: Yuji Kikukawa, Hiromasa Kitajima, Sho Kuwajima, Yoshihito Hayashi
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Molecules
Subjects:
calixarene-like structure
polyoxometalates
nitronate
crystal structure
host–guest chemistry
anion receptor
Online Access:https://www.mdpi.com/1420-3049/25/23/5670

Internet

https://www.mdpi.com/1420-3049/25/23/5670

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