Relative reactivity of the dinuclear ruthenium complex [CpRu(CO)2]2 with diphenylselenyl sulphide and diphenyl disulphide
The reaction of the diruthenium complex [CpRu(CO)2]2 with the diphenyl dichalcogenides was found to proceed through photoinitiation to the [CpRu(CO)2]· radical. Reaction with selenyl sulphide was slower than with disulphide, which has implications for the selective targeting of the enzyme thioredoxi...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2021-01-01
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| Series: | Results in Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715621000643 |