β,β-Isomer of Open-Wells–Dawson Polyoxometalate Containing a Tetra-Iron(III) Hydroxide Cluster: [{Fe4(H2O)(OH)5}(β,β-Si2W18O66)]9−

β,β-Isomer of Open-Wells–Dawson Polyoxometalate Containing a Tetra-Iron(III) Hydroxide Cluster: [{Fe4(H2O)(OH)5}(β,β-Si2W18O66)]9−

The β,β-isomer of open-Wells–Dawson polyoxometalate (POM) containing a tetra-iron(III) cluster, K9[{Fe4(H2O)(OH)5}(β,β-Si2W18O66)]·17H2O (potassium salt of β,β-Fe4-open), was synthesized by reacting Na9H[A-β-SiW9O34]·23H2O with FeCl3·6H2O at pH 3, and characterized by X-ray crystallography, FTIR, el...

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Bibliographic Details
Main Authors: Satoshi Matsunaga, Eriko Miyamae, Yusuke Inoue, Kenji Nomiya
Format: Article
Language:English
Published: MDPI AG 2016-05-01
Series:Inorganics
Subjects:
polyoxometalates
open-Wells–Dawson structural POM
iron
geometrical isomer
Online Access:http://www.mdpi.com/2304-6740/4/2/15

Internet

http://www.mdpi.com/2304-6740/4/2/15

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